You're not being stupid. A few hundred writes a day on one server is a tiny load for SQLite. Postgres wouldn't make it faster for you.
But one thing needs fixing now: cp of a live SQLite file can produce a corrupt backup if a write happens during the copy (especially in WAL mode, where recent data is in the -wal file). Use the backup API instead:
sqlite3 app.db ".backup '/backups/app-$(date +%F).db'"or VACUUM INTO, or Litestream for continuous backups to S3-compatible storage. Test a restore once.
The real reasons to move later: you need a second app server, or several processes writing heavily, or you want managed backups and point-in-time restore without running them yourself.